Previously unpublished water adsorption isotherm related to the publication: Confined water cluster formation in water harvesting by metal organic frameworks: CAU-10-H versus CAU-10-CH? by van der Veen et al. in Advanced Materials 2023, https://doi.org/10.1002/adma.202210050 . The numbering of the samples (e.g. 1. BioMOF(Ba)) refers to the position of the sample in Table S7 in the supporting information of the publication.
All the samples were activated before the sorption measurement. Details of the measurement follow here.  The .csv files related to each measurements contain three colums: Relative Pressure (p/p); Absolute Pressure (mmHg);Quantity Adsorbed (mmol/g).  p refers to the saturation pressure of water at the temperature of the measurement.
;; 
1. BioMOF(Ba)





3Flex 4.04
3Flex Version 3.00
Page 1



Serial # 215  Unit 1  Port 1











Sample:
BioMOFBa


Operator:
Willy



Sample owner:
Thais



File:
D:\3Flex Data\Data2015\2015-V-104.SMP










Started:
16-06-15 13:41:17
Analysis adsorptive:
H2O

Completed:
19-06-15 08:48:17
Analysis bath temp.:
313.000 K
Report time:
05-06-20 15:33:02
Thermal correction:
No

Sample mass:
0.0815 g
Ambient free space:
22.0684 cm Measured
Analysis free space:
21.6012 cm
Equilibration interval:
40 s

Low pressure dose:
None
Sample density:
1.000 g/cm
Automatic degas:
No




8. CAU-10-H




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 1








Sample:
CAU-10-H pellets (TZ-P29R10)
Operator:
Martijn


Sample owner:
Martijn


File:
D:\3Flex Data\Data2015\2015-V-032.SMP








Started:
07-04-15 12:31:57
Analysis adsorptive:
H2O
Completed:
12-04-15 00:33:46
Analysis bath temp.:
313.000 K
Report time:
08-06-20 16:42:46
Thermal correction:
No
Sample mass:
0.1087 g
Ambient free space:
22.3530 cm Measured
Analysis free space:
21.7069 cm
Equilibration interval:
30 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



12. Co-CUK-1




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 1








Sample:
Co-CUK-1 (rood)

Operator:
KRICT


Sample owner:
Martijn


File:
D:\3Flex Data\Data2015\2015-V-163.SMP








Started:
03-09-15 11:26:14
Analysis adsorptive:
H2O
Completed:
09-09-15 00:18:36
Analysis bath temp.:
298.000 K
Report time:
09-06-20 18:32:02
Thermal correction:
No
Sample mass:
0.0911 g
Ambient free space:
22.3417 cm Measured
Analysis free space:
22.3417 cm
Equilibration interval:
30 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No




13. Mg-CUK-1




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 1








Sample:
Pellets: MG-CUK-1 (wit) x2
Operator:
KRICT


Sample owner:
Martijn


File:
D:\3Flex Data\Data2015\2015-V-169.SMP








Started:
15-09-15 11:32:32
Analysis adsorptive:
H2O
Completed:
21-09-15 19:58:45
Analysis bath temp.:
298.000 K
Report time:
09-06-20 18:39:03
Thermal correction:
No
Sample mass:
0.0871 g
Ambient free space:
22.1290 cm Measured
Analysis free space:
22.1290 cm
Equilibration interval:
30 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



14. MIL-100(Cr)




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 3








Sample:
MIL-100(Cr) 20-07-12
Operator:
Martijn


Sample owner:
Martijn


File:
D:\3Flex Data\Data2014\2014-V-042.SMP








Started:
23-06-14 10:38:58
Analysis adsorptive:
H2O
Completed:
01-07-14 12:54:54
Analysis bath temp.:
288.000 K
Report time:
08-06-20 16:12:41
Thermal correction:
No
Sample mass:
0.1626 g
Ambient free space:
21.8872 cm Measured
Analysis free space:
22.6228 cm
Equilibration interval:
30 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No




17. NH2-MIL-125




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 1









Sample:
MIL-125-NH2 (Krikt) with water, 60 s equilibr. 
Operator:
Martijn, Canan and Willy

Submitter:
Martijn


File:
D:\3Flex Data\Data2014\2014-V-001.SMP








Started:
03-04-14 16:39:07
Analysis adsorptive:
H2O
Completed:
07-04-14 13:53:07
Analysis bath temp.:
298.000 K
Report time:
05-06-20 15:06:19
Thermal correction:
No
Sample mass:
0.1045 g
Ambient free space:
22.1489 cm Measured
Analysis free space:
22.1489 cm
Equilibration interval:
60 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



18. NH2-MIL-125




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 2








Sample:
NH2-MIL-125[KRIKT] ex H2O
Operator:
Martijn


Sample owner:
Martijn


File:
D:\3Flex Data\Data2014\2014-V-041.SMP








Started:
23-06-14 10:38:58
Analysis adsorptive:
H2O
Completed:
01-07-14 12:54:54
Analysis bath temp.:
288.000 K
Report time:
08-06-20 16:12:41
Thermal correction:
No
Sample mass:
0.1122 g
Ambient free space:
21.9285 cm Measured
Analysis free space:
22.6101 cm
Equilibration interval:
30 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



19. NH2-MIL-125




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 3








Sample:
NH2-MIL-125 pellets 050913
Operator:
Martijn


Sample owner:
Martijn


File:
D:\3Flex Data\Data2015\2015-V-026.SMP








Started:
23-03-15 10:27:29
Analysis adsorptive:
H2O
Completed:
30-03-15 13:26:08
Analysis bath temp.:
298.000 K
Report time:
08-06-20 16:42:45
Thermal correction:
No
Sample mass:
0.1220 g
Ambient free space:
22.2908 cm Measured
Analysis free space:
22.2908 cm
Equilibration interval:
30 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



20. NH2-MIL-125




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 3








Sample:
NH2-MIL-125

Operator:
Martijn


Sample owner:
Martijn


File:
D:\3Flex Data\Data2015\2015-V-034.SMP








Started:
07-04-15 12:31:57
Analysis adsorptive:
H2O
Completed:
12-04-15 00:33:46
Analysis bath temp.:
313.000 K
Report time:
08-06-20 16:42:46
Thermal correction:
No
Sample mass:
0.1078 g
Ambient free space:
22.2539 cm Measured
Analysis free space:
21.6329 cm
Equilibration interval:
30 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



21. Ni-CUK-1




3Flex 4.04
3Flex Version 3.00
Page 1


Serial # 215  Unit 1  Port 3








Sample:
Ni-CUK-1 (groen)

Operator:
KRICT


Sample owner:
Martijn


File:
D:\3Flex Data\Data2015\2015-V-165.SMP








Started:
03-09-15 11:26:14
Analysis adsorptive:
H2O
Completed:
09-09-15 00:18:37
Analysis bath temp.:
298.000 K
Report time:
09-06-20 18:41:03
Thermal correction:
No
Sample mass:
0.1018 g
Ambient free space:
22.2822 cm Measured
Analysis free space:
22.2822 cm
Equilibration interval:
30 s
Low pressure dose:
0.10000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



22. SIFSIX-3-Ni




3Flex 4.04
3Flex Version 4.04
Page 1


Serial # 215  Unit 1  Port 3








Sample:
SIFSIX exp. 4.3

Operator:
Willy Rook

Sample owner:
Thijn van de Ven / Xuerui Wang
File:
D:\3Flex Data\Data2018\2018-V-003.SMP








Started:
08-05-18 15:10:29
Analysis adsorptive:
H2O
Completed:
13-05-18 04:23:46
Analysis bath temp.:
293.000 K
Report time:
13-05-18 04:23:46
Thermal correction:
No
Sample mass:
0.1314 g
Ambient free space:
22.4007 cm Measured
Analysis free space:
22.5876 cm
Equilibration interval:
40 s
Low pressure dose:
0.20000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



23. SIFSIX-3-Ni




3Flex 4.04
3Flex Version 4.04
Page 1


Serial # 215  Unit 1  Port 1








Sample:
SIFSIX-3-Ni-96-60 N2 phys (repeat)
Operator:
Willy


Sample owner:
Christian / Xuerui

File:
D:\3Flex Data\Data2019\2019-V-003.SMP








Started:
25-06-19 11:22:23
Analysis adsorptive:
H2O
Completed:
01-07-19 10:33:41
Analysis bath temp.:
293.000 K
Report time:
05-06-20 17:42:54
Thermal correction:
No
Sample mass:
0.1105 g
Ambient free space:
22.5042 cm Measured
Analysis free space:
22.6106 cm
Equilibration interval:
40 s
Low pressure dose:
0.25000 mmol/g
Sample density:
1.000 g/cm
Automatic degas:
No



24. ZIF-90




3Flex 4.04
3Flex Version 4.04
Page 1


Serial # 215  Unit 1  Port 1








Sample:
JW135 - ZIF-90, repeat
Operator:
Willy Rook

Sample owner:
Justus Weustink

File:
D:\3Flex Data\Data2020\2020-V-010.SMP








Started:
06-02-20 10:24:32
Analysis adsorptive:
H2O
Completed:
09-02-20 10:04:37
Analysis bath temp.:
293.000 K
Report time:
05-06-20 14:32:39
Thermal correction:
No
Sample mass:
0.0797 g
Ambient free space:
22.2884 cm Measured
Analysis free space:
22.4279 cm
Equilibration interval:
40 s
Low pressure dose:
None
Sample density:
1.000 g/cm
Automatic degas:
No



