Data underlying the publication: Capturing CO₂ under Dry and Humid Conditions: When Does the Parent MOF Outperform the MTV MOF?

-Folder structure and content:

3D-ED: Contains the 3D electron diffraction data and a report provided by Dr. Khai-Nghi Truong from Rigaku Europe SE.

Adsorption: Includes single-component adsorption data and CO₂–H₂O competitive adsorption data.

ATR-IR: Contains the infrared (IR) spectra collected for all materials.

Elemental Analysis: Includes a report from Mikroanalytisches Laboratorium Kolbe.

PXRD: Contains powder X-ray diffraction (PXRD) patterns of both as-synthesized and activated materials.

SEM: Contains scanning electron microscopy (SEM) images of the materials.

TGA: Contains thermogravimetric analysis (TGA) data of the materials.

XPS: Contains X-ray photoelectron spectroscopy (XPS) data of the materials.

-Methodological information:
Details on the instrumentation, measurement parameters, and data processing methods are provided in the Supporting Information of the publication.

-Data-specific information:
The sample codes for each MOF studied are listed below:

SAN3.1 (MIL-53-NH₂)

SAN12 (MIL-53-0.75NH₂-0.25CH₃)

SAN9 (MIL-53-0.50NH₂-0.50CH₃)

SAN11 (MIL-53-0.25NH₂-0.75CH₃)

SAN13 (MIL-53-0.10NH₂-0.90CH₃)

SAN14 (MIL-53-0.05NH₂-0.95CH₃)

SAN8 (MIL-53-CH₃)

SAN10 (MIL-53)

For single-component adsorption measurements, all raw data have been converted to the standardized .aif (Adsorption Information File) format.